By default Windows XP will not allow hard drives larger than 32gb to be formatted FAT32. If you need to format a large hard drive to FAT32 (say for an external hard drive to make backups of your Windows and Mac workstations) you can a tool provided by Ridgecrop Consultatnts called Fat 32 Formatter.
Documentation and Product Page
http://www.ridgecrop.demon.co.uk/index.htm?fat32format.htm
Download
http://www.ridgecrop.demon.co.uk/download/fat32format.zip
Usage
C:\> cd path\to\fat32format
C:\> fat32format f:
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Tags: fat32, format, larger than 32gb
